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Larreal-RamirezPagecations and anions [62]; the formation of such chains could also be true of the calcium phosphate prenucleation clusters. 2.2 Pathologic Calcification: Role of IDPs Calcifications occurring in unwanted places ?the aorta, salivary glands and soft tissues, are all associated with IDPs. To illustrate, salivary stones occur when mucins, such as statherin, an un-folded protein [63],
Tructures on binding. 2.4 Self-Assembly of IDPs IDPs frequently undergo self-assembly. The extended conformation of IDPs facilitates the intermolecular interactions between them and promotes formation of supramolecular architecture [109]. This is illustrated in some of the mineralized tissues discussed above. Silaffins, for example, are protein constituents of biosilica, playing an active role in
The transformation to a crystalline phase and in others providing a means for remaining in an amorphous state. Some of these amorphous structures have short range order [117] and may be considered proto-crystalline [116]. For amorphous calcium carbonate, this short range order is only noted in the presence of additives, such as poly-aspartic acid. Since the amorphous structures aggregate to form

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